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| author | Anton Luka Šijanec <anton@sijanec.eu> | 2022-05-19 07:26:12 +0200 |
|---|---|---|
| committer | Anton Luka Šijanec <anton@sijanec.eu> | 2022-05-19 07:26:12 +0200 |
| commit | b250709f6d6ac090e0ca37a56afd8cdc48cb0533 (patch) | |
| tree | 482dd0342cefdc35b73c050815c74fcfc0481e91 /kem | |
| parent | učenje kemije za zadnji test (upajmo) (diff) | |
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Diffstat (limited to 'kem')
| -rw-r--r-- | kem/test.md | 3 |
1 files changed, 3 insertions, 0 deletions
diff --git a/kem/test.md b/kem/test.md index 6d94d86..39c08c3 100644 --- a/kem/test.md +++ b/kem/test.md @@ -146,6 +146,7 @@ Organska kemija * adicija vode - hidriranje: CH3-CH=CH2 + H-OH -> (v kislem) CH3-CHOH-CH3 (alkohol) * na alkine adicije potekajo v dveh stopnjah - hidriranje: CH3-CH2-C≡CH + H2O -> (HgSO4/H+) CH3-CH2-C(-OH)=CH2 <-> CH3-CH2-C(=O)-CH3 + + trojne vezi v substratu med C in CH se ne vidi na PDFju! ### aromatske spojine @@ -306,8 +307,10 @@ Organska kemija - CH3-C(=O)-CH3 + HCN -> CH3-(HO-)C(-CN)-CH3 * adicija HCN na etanal in sledeča kislinsko katalizirana hidroliza v 2-hidroksipropanojsko kislino - CH3-C(=O)-H + HCN -> CH3-(HO=)CH-C≡N -> (H2O/H+ kislinsko katali. hidrol.) CH3-(HO=)CH-COOH + + v nitrilu v drugi stopnji je med C in N seveda trojna vez, v PDFju je ni * katalizirana adicija vodika na 2-hidroksipropannitril v 1-aminopropan-2-ol - CH3-(HO-)CH-C≡N -> (H2/Pt) CH3-(HO-)CH-CH2-NH2 + + v substratu je med C in N seveda trojna vez, ki pa je v PDFju ni * adicija natrijevega hidrogensulfata(IV): CH3-CH2-C(=O)-H + NaHSO3 -> CH3CH2-(HO-)C(-SO3Na)-H ### nastanek estrov |